• representations of atoms to help visualize atomic structure, and explain/predict the behaviour of atoms
  • every model sacrifices some accuracy for simplicity, visibility, or usability
Atom models
Khan Academy, CC BY-NC-SA 3.0

The Bohr model

Bohr model of various atoms
Bohr model of various atoms. Khan Academy, CC BY-NC-SA 3.0
  • represents electrons as particles that occupy specific, quantized energy levels
  • electrons are represented as black dots that sit on a ring around the nucleus
  • nucleus is a single circle in the center
  • not meant to represent what real atoms look like

Strengths

  • represents the particle nature of electrons, easy to see the number of electrons in an atom
  • electrons exist at specific energy levels, Bohr model represents these as rings
    • electrons on the same ring are at the same energy level

Weaknesses

  • does not reflect the wave properties of electrons
    • electrons appear to exist in specific locations, which is not entirely true
  • nucleus is shown as single circle, no distinct protons/neutrons
  • because it treats electrons as having fixed orbits, it can not accurately predict the atomic spectra for more complex atoms with more than one electron

The de Broglie model

the de Broglie atomic model
Larry Sulak, Boston U.
  • electrons are represented as a physical standing wave around the nucleus
  • higher energy levels show wave patterns with more segments, like a vibration string
  • does not handle the particle behaviour of electrons

The electron cloud model

Electron cloud model of a helium atom
"Helium atom QM" by Yzmo, CC BY-SA 3.0
  • also called the quantum mechanical model, and sometimes the Schrödinger model
  • expanded on de Broglie’s wave model to mathematically describe electron behaviour
  • instead of electrons being at fixed positions, it predicts the probability distribution for where electrons are likely to be found
  • the nucleus is a group of individual red protons and purple neutrons
  • regions around the nucleus, orbitals, show the probability of finding an electron
  • electron transitions are represented as transitions from one harmonic to another in the wave function
  • Schrödinger equation, wave function

Strengths

  • represents the wave and particle behaviour of electrons
    • fuzzy electron cloud represents how individual electrons are distributed in the atom
    • until we measure the position of an electron, we don’t know exactly where it is, the best we can do is describe where they are likely to be found around the nucleus
  • how the nucleus is represented
    • individual protons and neutrons
    • very small compared to the size of the electron cloud
      • real nucleus would be invisible if properly scaled in this model

Weaknesses

  • does not represent the particle nature of electrons
    • can’t tell how many electrons an atom has